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WBJEEAmong the following options, select the option in which each complex in Set-I...
Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.
\(\text { [en } \left.=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2\right]\)
\(\text { [en } \left.=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2\right]\)
Solution:
Set-I: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]\) and \(\left[\mathrm{Co}(e n)_2 \mathrm{Cl}_2\right]\)
Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}\)
Set-I:
Set-II:
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{SO}_4\right] \mathrm{Cl}\) are ionisation isomers.
Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}\)
Set-I:
Set-II:
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{SO}_4\right] \mathrm{Cl}\) are ionisation isomers.
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