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For the process H2O(l) (1 bar, \(\left.273 \mathrm{~K}\right) \longrightarrow \mathrm{H}_2 \mathrm{O}(\m…
Statement 1 For every chemical reaction at equilibrium, standard Gibbs energy of reaction is zero. Statement 2 At constant temperature an…
Statement 1 There is a natural asymmetry between converting work to heat and converting heat to work. Statement 2 No process is possible …
Among the following, the state function(s) is (are) internal energy irreversible expansion work re…
Among the following, intensive property is (properties are) molar conductivity electromotive force …
The species which by definition has zero standard molar enthalpy of formation at 298 K is \(\mathr…
Match the transformation in Column I with appropriate options in Column II. (A) p,q,r,s, (B) r,s, (C) t, (D) p,q…
For an ideal gas, consider only P-V work in going from an initial state X to the final state Z. The final state…
The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which of the following stateme…
Using the data provided, calculate the multiple bond energy (kJmol−1) of a \(\mathrm{C} \equiv \math…
The standard enthalpies of formation of  C O 2 ( g )   , H 2 O l and glucose (s) at 2 5 o C are  - 400 kJ / mol…
Paragraph: A fixed mass ' m ' of a gas is subjected to transformation of states from K to L  to M to N and back to K as sh…
Paragraph: A fixed mass ' m ' of a gas is subjected to transformation of states from K to L  to M to N and back to K as sh…
An ideal gas in a thermally insulated vessel at internal pressure = P 1 , volume = V 1 and absolute temperature = T 1 expands irrevers…
For the process H 2 O   l → H 2 O g   at T = 100 o C   and 1 atmosphere pressure, the correct choice is ∆ S s …
Match the thermodynamic processes given under Column I with the expressions given under Column II.   Column I   Colu…
One mole of an ideal gas at 300   K in thermal contact with its surroundings expands isothermally from 1 . 0   L  to  2 . 0   L  against…
For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium constant K …
The standard state Gibb's free energies of formation of  C  (graphite) and C  (diamond) at T = 298   K are Δ f G o C   ( graphite = …
For a reaction, A ⇌ P , the plots of   A a n d   P with time at temperatures T 1   a n d   T 2 are given below. If T 2 > T 1 , the…