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Choose the correct statement(s) among the following: FeCl4- has tetrahedral geometry. Co(en)NH32Cl2+ has 2...

Choose the correct statement(s) among the following:
FeCl4- has tetrahedral geometry.
Co(en)NH32Cl2+ has 2 geometrical isomers.
FeCl4- has higher spin-only magnetic moment than Co(en)NH32Cl2+
The cobalt ion inCo(en)NH32Cl2+has sp3d2 hybridization.
Solution:

(A) FeCl4-

Oxidation number of Fe atom =+3

Fe3d64s2

Fe3+3d5

 FeCl4- is having tetrahedral geometry

(B) Co(en)NH32+ have three geometrical isomers.

(C) FeCl4- is sp3 hybridized with 5 -unpaired electrons. While Co(en)NH32Cl2+ is d2sp3hybridised with zero unpaired electrons.

(D) Co(en)NH32Cl2+ has d2sp3 hybridization.