Match each set of hybrid orbitals from LIST-I with complex (es) given in...
Match each set of hybrid orbitals from LIST-I with complex (es) given in LIST-II.
LIST -I | LIST -II | ||
A) | dsp2dsp2 | P) | [FeF6]4-[FeF6]4− |
B) | sp3sp3 | Q) | [Ti(H2O)3Cl3][Ti(H2O)3Cl3] |
C) | sp3d2sp3d2 | R) | [Cr(NH3)6]3+[Cr(NH3)6]3+ |
D) | d2sp3d2sp3 | S) | [FeCl4]2-[FeCl4]2− |
T) | Ni(CO)4Ni(CO)4 | ||
U) | [Ni(CN)4]2-[Ni(CN)4]2− |
Solution:
(P)(P) [FeF6]4-[FeF6]4−

(Q)(Q) [Ti(H2O)3Cl3][Ti(H2O)3Cl3]

(R) [Cr(NH3)6]3+

(S) [FeCl4]2-

(T) [Ni(CO)4]
Ni :3d8eS2

Back pairing of elements due to pressure of strong field ligand

(U) [Ni(CN)4]2-
NI2+ :3d8


(Q)(Q) [Ti(H2O)3Cl3][Ti(H2O)3Cl3]

(R) [Cr(NH3)6]3+

(S) [FeCl4]2-

(T) [Ni(CO)4]
Ni :3d8eS2

Back pairing of elements due to pressure of strong field ligand

(U) [Ni(CN)4]2-
NI2+ :3d8

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