NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature depend-ent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of...
NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature depend-ent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are respectively
Solution:
In both states (paramagnetic and diamagnetic) of the given complex, Ni exists as Ni2+ whose electronic configuration is [Ar]3d84s0.

In the above paramagnetic state the geometry of the complex is sp3 giving tetrahedral geometry.
The diamagnetic state is achieved by pairing of electrons in 3d orbital.
Thus, the geometry of the complex will be dsp2 giving square planar geometry.

In the above paramagnetic state the geometry of the complex is sp3 giving tetrahedral geometry.
The diamagnetic state is achieved by pairing of electrons in 3d orbital.

Thus, the geometry of the complex will be dsp2 giving square planar geometry.
Join the conversation