Loading [MathJax]/jax/output/CommonHTML/jax.js
All
BE/B.Tech
MBA/PGDM
MBBS
ME/M.Tech
B.Sc
BA
B.Com
BCA
BBA/BMS
B.Sc (Nursing)

Ranking

College ranked based on real data

Indiatoday - 1740
Collegedunia - 1406
IIRF - 1684
Outlook - 1318
NIRF - 1301
Top Ranked Colleges in India ›

Find Colleges

Discover 19000+ colleges via preferences

Best MBA colleges in India
Best BTech colleges in India
Discover Top Colleges in India ›

Compare Colleges

Compare on the basis of rank, fees, etc.

IIT Madras vs IIT Delhi
IIT Madras vs IIT Bombay
Compare Colleges ›

Exams

Know more about your exams

B.Com
B.Sc
B.Sc (Nursing)
BA
BBA/BMS
BCA
BE/B.Tech
Check All Entrance Exams in India ›

College Predictor

Know your college admission chances

JEE Main
JEE Advanced
CAT
NEET
GATE
NMAT
MAT
XAT
Find Where you may get Admission ›

Course Finder

Discover top courses in Indian Colleges 2025

BE/B.Tech - 963
MBA/PGDM - 1159
ME/M.Tech - 1221
B.Sc - 1052
Get Top Courses in Indian Colleges ›

Your Gateway to Top Colleges & Exams

Discover thousands of questions, past papers, college details and all exam insights – in one place.

Popular Colleges

Top Exams

JEE MainJEE Main
JEE AdvJEE Advanced
NEET UGNEET UG
BITSATBITSAT
COMEDKCOMEDK
VITEEEVITEEE
WBJEEWBJEE

NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature depend-ent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of...

NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature depend-ent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are respectively
tetrahedral and tetrahedral
square planar and square planar
tetrahedral and square planar
square planar and tetrahedral
Solution:
In both states (paramagnetic and diamagnetic) of the given complex, Ni exists as Ni2+ whose electronic configuration is [Ar]3d84s0.




In the above paramagnetic state the geometry of the complex is sp3 giving tetrahedral geometry.

The diamagnetic state is achieved by pairing of electrons in 3d orbital.


Thus, the geometry of the complex will be dsp2 giving square planar geometry.