Paragraph:p-amino-N, N-dimethylaniline is added to a strongly acidic solution of X. The resulting...
Paragraph:
p-amino-N, N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of Y with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves an excess addition of the reagent. Similarly, treatment of the solution of Y with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of Z.Question:
The compound Z, is
p-amino-N, N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of Y with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves an excess addition of the reagent. Similarly, treatment of the solution of Y with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of Z.Question:
The compound Z, is
Solution:
p-amino- N, N-dimethylaniline reacts with sulphide ion (S2−) in presence of Fe3+ ion to form blue coloured solution of methylene blue :


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