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The complex showing a spin-only magnetic moment of 2.82 B.M. is Ni(CO)4 [NiCl4]2−...

The complex showing a spin-only magnetic moment of 2.82 B.M. is

Ni(CO)4

[NiCl4]2−

Ni(PPh3)4

[Ni(CN)4]2−
Solution:
Ni:3d84s2Ni2+:3d8
Since, Cl is a weak field ligand, it doesn't cause pairing of electron.


Number of unpaired electrons, n=2

\mu=\sqrt{n(n+2)}=\sqrt{2(2+2)} \mathrm{BM}=\sqrt{8} \mathrm{BM}=2.82 \mathrm{BM}

Coordination compound
Conceptual
III